What you seem (to me) to be asking is under which conditions on a Lorentzian manifold its Alexandrov topology not even $T_0$. If that is the case, then it is easy to see that if $(M,g)$ is not chronological then the Alexandrov topology cannot be $T_0$. More precisely, one can show that pairs of points lying in some closed timelike curve cannot be separated by the Alexandrov topology.
To wit, let $p,q\in M$ such that $p\ll q$ and $q\ll p$, where $\ll$ is the chronology relation (a strict partial order) on $(M,g)$. Let now $r,s\in M$ such that $r\ll p\ll s$ so that $p\in(r,s)\doteq\{t\in M\ |\ r\ll t\ll s\}$, recalling that subsets of the form $(r,s)$ for $r\ll s$ form a basis for the Alexandrov topology of $(M,g)$. Since $p\ll q$ (resp. $q\ll p$), we have that $r\ll q$ (resp. $q\ll s$), therefore $q\in(r,s)$ as well. This already shows that the Alexandrov topology is not $T_1$, but since the roles of $p,q$ above are symmetric, we also conclude that the Alexandrov topology is not even $T_0$, as claimed.
The above argument shows that the $T_0$ condition for the Alexandrov topology is a sufficient condition for the chronology condition on $(M,g)$ to hold. R. Penrose provides examples (see Techniques of Differential Topology in Relativity, SIAM, 1972, particularly Remark 4.25, pp. 34) of weaker failures of separation conditions for the Alexandrov topology - more precisely:
- A (future- and past-)distinguishing space-time $(M,g)$ in which the Alexandrov topology is $T_1$ but not Hausdorff (see Figure 23, pp. 29 of R. Penrose, ibid.);
- A distinguishing space-time $(M,g)$ in which the Alexandrov topology is not $T_1$ (see Figure 26, pp. 35 of R. Penrose, ibid.). This example does seem to be $T_0$ with respect to the Alexandrov topology, though.
Both these examples, being distinguishing, are causal and hence chronological. It is not clear to me whether (let alone how) separation conditions below the Hausdorff condition for the Alexandrov topology on a Lorentzian manifold $(M,g)$ fit into the causal ladder of space-time conditions between chronology and strong causality, though.