The answer depends on what you mean by "one-to-one correspondence". Is it bijective or just injective? Robert Bryant's (standard) argument shows that $\mathbb R^N/\mathrm{SO}(n)\to \mathrm{AlgHom}_{\mathbb R}(A,\mathbb R)$ is injective. In general, this map is very far from being surjective, though. In other words, not every Homomorphism $A\to\mathbb R$ is an evaluation map.
Already the standard action of $\mathrm{SO}(n)$ on $\mathbb R^n$ is a counterexample. In this case, $A=\mathbb R[q]$ where $q(v)=\|v\|^2$ is the norm square function. Thus a homomorphisms $f:A\to\mathbb R$ is given by the value $f(q)$ which can be an arbitrary real number. But the image of $\mathbb R^n/\mathrm{SO}(n)$ is obviously only $\mathbb R_{\ge0}$.
So what is the "correct quotient"? The answer is "It depends". A topologist would say it is the orbit space. The embedding into $\mathrm{AlgHom}_{\mathbb R}(A,\mathbb R)$ gives the orbit space the structure of a semialgebraic set on which you have notions of continuous or smooth function. A theorem of G. Schwarz states that all continuous/smooth invariants are pull-backs of continuous/smooth function on the orbit space.
An algebraist would prefer to call $\mathrm{AlgHom}_{\mathbb R}(A,\mathbb R)$ to be the quotient since it classified all closed orbits defined over $\mathbb R$ regardless whether the contain a real point or not.
A very nice paper calculating the image of $\mathbb R^N/\mathrm{SO}(n)\to \mathrm{AlgHom}_{\mathbb R}(A,\mathbb R)$ (in particular) in terms of inequalities is Procesi, Claudio; Schwarz, Gerald: Inequalities defining orbit spaces.
Invent. Math. 81 (1985), 539–554