A counterexample is given by the following conditions: $n=185$,
$$a_k=\sum_{j=k}^n b_j,\quad b_j:=\frac{c_j}{j+1},
\quad c_j:=\frac{1000}7\,1(j=47)+\frac{302}7\,1(j=185).$$
Indeed, then $a_0\ge\cdots\ge a_n\ge0$,
$$s_0:=\sum_{k=0}^n a_k=\sum_{k=0}^n \sum_{j=k}^n b_j
=\sum_{j=0}^n b_j\sum_{k=0}^j 1 \\
=\sum_{j=0}^n b_j(j+1)
=\sum_{j=0}^n c_j=\frac{1000}7+\frac{302}7=186\in[n+1,n+2],$$
$$s_1:=\sum_{k=0}^n(k+1)a_k=\sum_{k=0}^n(k+1)\sum_{j=k}^n b_j
=\sum_{j=0}^n b_j\sum_{k=0}^j(k+1) \\
=\sum_{j=0}^n b_j\frac{(j+1)(j+2)}2
=\sum_{j=0}^n c_j\frac{j+2}2=\frac{105474}7,$$
$$s_2:=\sum_{k=0}^n k(k+1)a_k=\sum_{k=0}^n k(k+1)\sum_{j=k}^n b_j
=\sum_{j=0}^n b_j\sum_{k=0}^j k(k+1) \\
=\sum_{j=0}^n b_j\frac{j(j+1)(j+2)}3
=\sum_{j=0}^n c_j\frac{j(j+2)}3=\frac{4250230}7,$$
so that the left-hand side of your inequality is
$$2s_1^2-(1+s_0)s_2=-\frac{1168732}{49}<0.\quad\Box$$