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Not quite adjoint functors

What are standard and/or natural examples of pairs of functors $F:C\leftrightarrows D:G$ and unnatural bijections $\hom_D(Fx,y)\to\hom_C(x,Gy)$ for all $x$ and $y$? Can one do this so that the ...
Mariano Suárez-Álvarez's user avatar