Here is a sketch, which can be completed to a proof.
Asymptotically (i.e. for $k$ large), $\ln\left(\frac{\pi}{2\arctan k}\right) = \frac{2}{\pi k} + O(\frac{1}{k^2})$. Sum termwise to get
$$\frac{2\Psi(2n+1)}{\pi} - \frac{2\Psi(n)}{\pi} + \sum_{k=n}^{2n} O(\frac{1}{k^2})$$
Use the propreties of $\Psi$ to simplify this to
$$\frac{2\ln 2}{\pi} + \frac{\Psi(n+1/2)}{\pi} -\frac{\Psi(n)}{\pi} + \sum_{k=n}^{2n} O(\frac{1}{k^2}) $$
Now, for $n$ large, this is asymptotically
$$\frac{2\ln 2}{\pi} + O(\frac{1}{n}).$$
All the terms in the product at positive, so taking the logarithm was legitimate. The termwise sum can similarly be justified.