Given a set $A \subset \mathbb{R}^n$, this is called d-rectifiable if it can be covered by a countable union of images of lipshitz functions from $\mathbb{R}^d $ to $ \mathbb{R}^n $ and a $\mathcal{H}^d$ null set. So given $A_j = f_j (\mathbb{R}^d)$ with $f_j$ Lipshitz, one has that A is d-rectifiable if
$$ A \subset \cup_{j=1} ^\infty A_j \cup A_0 \text{ where } \mathcal{H}^d (A_0)=0 .$$
Now, consider $d=1$ and $n=2$ for simplicity. If I consider a countable number of "bad points", I wouldn't really need that $A_0$ in the definition. The only relevant case is when the cardinality of $A_0$ is more than countable.
Now the question is the following. I know there is the structure theorem by Federer-Fleming which tells you that you can decompose any $\mathcal{H}^d $- measurable set of finite measure in a rectifiable part and in a purely unrectifiable part. Let's call this set $A$, the rectifiable part $A^{rect}$ and the unrectifiable part $A^{unr}$. Given the definition above, the only relevant case is when $\mathcal{H}^d (A^{unr}) >0$, otherwise one could consider it to be the null set in the definition, making $A$ rectifiable.
The question is: why did we choose to define rectifiability that way and not without $A_0$? I mean, one could take $A^{rect}$ to be the union of the $A_j$s above, while discarding the $A_0$ in the unrectifiable part. It somehow seems to even make more sense, you could partition a set $A$ in a good part which is ALL contained in unions of images of Lipshitz functions, and in a bad part which contains all the rest. Is this just a convention or there's some good reason to have this definition? I guess it has to do with the fact of wanting to have some "compactness" in the class of rectifiable sets, meaning that a perturbation by a null set don't make you go out of the class, but maybe there's a deeper reason.