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Are there infinitely many ones in the simple continued fraction for pi? I know that there’s a probability distribution given through Gauss-Kuzmin, but is there a proof that there’s infinitely many ones? How about proofs that there are infinitely many of any positive integer in pi’s simple continued fraction?

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Nothing like that is known. There is likewise no proof that the decimal expansion of $\pi$ has infinitely many 1's (or any other specific digit).

The continued fraction expansions of algebraic numbers of degree greater than $2$ are equally opaque: none are known to have any specific positive integer appearing in them infinitely often. And the decimal expansion of no specific irrational algebraic number is proved to contain a specific digit infinitely often even though of course we expect each digit appears equally often.

These kinds of things are just hopeless to expect to be provable at present.

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