Koenigsmann's result was generlized by Jennifer Park to number fields, giving a universal definition of the ring of integers $\mathcal{O}_K$ in $K$. Then there is a series of results proving that $\mathbb{Z}$ is existentially definable in $\mathcal{O}_K$ for certain $K$, starting I think with results by Jan Denef (totally real number fields, or quadratic extension of a totally real field). Combining the two, one gets an $\exists\forall$-definition of $\mathbb{Z}$ in $K$ at least for these number fields.
It is possible though that one also has an $\forall$-definition of $\mathbb{Z}$ in $K$ for some number fields $K\neq\mathbb{Q}$, but I don't remember right now.