Your question can be equivalently phrased as:
Given a closed two-form $F$ on $\mathbb{R}^4$, is it always possible to find a Lorentzian metric on $\mathbb{R}^4$ such that $\delta F = 0$.
Then the answer is, in general, no.
First, consider the case if you require $(\mathbb{R}^4,g)$ to be globally hyperbolic.
Counterexample:
Let $A$ be non-closed, compactly supported one form on $\mathbb{R}^4$. Its exterior derivative $F = dA$ is closed, compactly supported, and not identically zero.
Suppose $g$ is globally hyperbolic. Then by the compact support of $F$ there exists a Cauchy hypersurface $\Sigma$ of $(\mathbb{R}^4, g)$ such that $F, \nabla F$ restricts to zero along $\Sigma$. By the uniqueness of solutions to hyperbolic PDEs, since $dF = \delta F = 0$, this implies $F \equiv 0$, contradicting the original assumption. Q.E.D.
The same argument can be localized as follows:
- Start with the same compactly supported (in space-time) non-trivial $F$.
- Suppose, for contradiction, that there exists a metric $g$ that does the job.
- Find a point $x$ on $\partial~\mathrm{supp}~ F$ such that the boundary is space-like with respect to $g$.
- Let $\Sigma$ be a space-like hypersurface through $x$ such that $\mathrm{supp}~ F$ is, in a causal convex neighborhood of $x$, to the future of $\Sigma$.
- Within the convex neighborhood we can find a globally hyperbolic neighborhood of $x$ for which $\Sigma$ is Cauchy. Running the argument above we see that $F$ must vanish identically in this neighborhood, which means that $x$ cannot in fact be on the boundary of $F$'s support. A contradiction.