I was helping a student study for a functional analysis exam and the question came up as to when, in practice, one needs to consider the Banach space $L^p$ for some value of $p$ other than the obvious ones of $p=1$, $p=2$, and $p=\infty$. I don't know much analysis and the best thing I could think of was Littlewood's 4/3 inequality. In its most elementary form, this inequality states that if $A = (a_{ij})$ is an $m\times n$ matrix with real entries, and we define the norm $$\|A\| = \sup\biggl(\left|\sum_{i=1}^m \sum_{j=1}^n a_{ij}s_it_j\right| : |s_i| \le 1, |t_j| \le 1\biggr)$$ then $$\biggl(\sum_{i,j} |a_{ij}|^{4/3}\biggr)^{3/4} \le \sqrt{2} \|A\|.$$ Are there more convincing examples of the importance of "exotic" values of $p$? I remember wondering about this as an undergraduate but never pursued it. As I think about it now, it does seem a bit odd from a pedagogical point of view that none of the textbooks I've seen give any applications involving specific values of $p$. I didn't run into Littlewood's 4/3 inequality until later in life.
[Edit: Thanks for the many responses, which exceeded my expectations! Perhaps I should have anticipated that this question would generate a big list; at any rate, I have added the big-list tag. My choice of which answer to accept was necessarily somewhat arbitrary; all the top responses are excellent.]