It appears from the figure 11.3.4 of dlmf that the Struve function $M_1(x)$ is monotonically decreasing for positive $x$. The asymptotic expansion (11.6.2) shows that the limit is $-2/\pi$. So it seems clear that
$$M_1(x)>-\frac{2}{\pi},\qquad x>0$$
But, how to prove this? Any hints or references much appreciated.
Edit: As indicated above, I am using dlmf definitions (11.2.2, 11.2.6):
$$M_\nu(z)=L_\nu(z)-I_\nu(z)$$ where $I$ is the modified Bessel function and
$$ L_\nu(z)=\left(\frac{z}{2}\right)^{\nu+1}\sum_{n=0}^\infty\frac{\left(\frac{z}{2}\right)^{2n}}{\Gamma\left(n+\frac32\right)\Gamma\left(n+\nu+\frac32\right)}$$
is the modified Struve function. The asymptotic expansion is given as (11.6.2):
$$ M_\nu(z)\sim\frac{1}{\pi}\sum_{k=0}^\infty(-1)^{k+1}\frac{\Gamma\left(k+\frac12\right)\left(\frac{z}{2}\right)^{\nu-2k-1}}{\Gamma\left(\nu+\frac12-k\right)},\qquad |z|\to\infty,\quad|\mbox{ph}(z)|\leq\frac{\pi}{2}-\delta$$