I need to answer (affirmatively, I hope) the following question:
In a Lie group $G$ whose Lie algebra $\mathfrak{g}$ is equipped with an $\mathrm{Ad}$-invariant scalar product, is the open subset $$\{g \in G \mid \operatorname{ker} (1 + \operatorname{Ad}_{g}) = \{0\}\}$$ dense in $G$?
In the case $G=\mathrm{GL}_n\mathbb{C}$, an affirmative answer goes as follows, which works for any complex reductive group as well. First we can restrict to the open dense subset $U$ of matrices with distinct eigenvalues. By conjugating any $g\in U$ to a diagonal matrix, we can see that $\mathrm{Ad}_g$ does not have eigenvalue $-1$ if and only if the proportion of any two eigenvalues is not $-1$, and this condition is dense.
However, since I'm writing an article in which everything else except this only relies on the property that $\mathfrak{g}$ is equipped with an $\mathrm{Ad}$-invariant scalar product, I feel like not to include the reductive assumption. But I fail to prove or find counterexamples to the above question in this case. In fact, I can't find any counterexample even for general Lie groups without any assumption.
Addendum As noticed by Peter McNamara, we should add the assumption that $G$ is connected, since for example in the case of the real orthogonal group $O(2n)$, the adjoint action of any elements not in the identity component has eigenvalue $-1$.