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What are the injective embeddings of R^d into the cone of (semi-) positive definite matrices of dimension d?

How can we characterize the set of all injective functions from $\mathbb{R}^d$ to the set of all symmetric positive definite matrices of dimension d?
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Carathéodory's theorem for $SO(3)$?

Let $Q \in \operatorname{Conv} SO(3)$. Is there a way to retrieve an explicit representation of $Q$ as convex combination $Q=\sum_{k=1}^{r}{\lambda_{i}R_{i}}, R_{i} \in SO(3)$? An approximation ...