OK, the "less demanding" question does seem more tractable; a few possible answers follow, though none is clearly the most "nice pleasant way of parametrizing" your curve. One direction leads to the trigonometric solution of a cubic equation with all roots real; the other leads to an elliptic curve with 6-torsion, and even to an extremal elliptic K3 surface! Which if any of these is best for you is a matter of taste and of what you're trying to do with these curves.
Let $(X,Y,Z) = (\sin^2 \alpha, \phantom.\sin^2 \beta, \phantom.\sin^2 \gamma)$. Then $(X,Y,Z)$ are coordinates of an algebraic curve
$$
E_c : X+Y+Z = c^2, \phantom{=} X^2+Y^2+Z^2 - 2(YZ+ZX+XY) + 4XYZ = 0.
$$
So far we've preserved the $S_3$ symmetry, and can recover the original variables via
$\alpha = \arcsin X^{1/2} = \frac12 \arccos(1-2X)$ and likewise for $\beta,\gamma$.
But this begs the question of what $E_c$ looks like, and leaves us with multivalued arcsines or arccosines. The latter problem seems inherent in another symmetry of the equation: we can translate $\alpha,\beta,\gamma$ by $a\pi,b\pi,c\pi$ for any integers $a,b,c$ with $a+b+c=0$. But we can try to do more with $E_c$.
One direction is to express everything in terms of elementary symmetric functions $\sigma_1,\sigma_2,\sigma_3$ of $X,Y,Z$, as R.Bryant did: the first equation says $\sigma_1=c^2$, and the second says $\sigma_1^2 = 4 (\sigma_3 - \sigma_2)$; so $(\sigma_1,\sigma_2,\sigma_3)$ are parametrized in terms of $\sigma_3$,
and then $X,Y,Z$ are the three roots of
$$
0 = u^3 - \sigma_1 u^2 + \sigma_2 u - \sigma_3 = u^3 - c^2 u^2 + (\sigma_3 + \tfrac14 c^4)u - \sigma_3.
$$
This is still manifestly symmetric but rather implicit. We we can solve the cubic; since it has three real roots the solution will involve trisecting some auxiliary angle $\theta$, itself given as the arccosine of some explicit but complicated algebraic function of $c$ and $\sigma_3$. The roots will then be given in terms of $c$, $\sigma_3$, and the cosines of $\theta/3$, $(\theta+2\pi)/3$, and $(\theta+4\pi)/3$, and the action of $S_3$ will correspond to replacing $\theta$ by the equivalent $\pm (\theta+2\pi n)$ for some $n \bmod 3$. This will be far from nice and pleasant (compare with the formulas for constructing a regular 13-gon using an angle trisector, as in p.192 of Gleason's Monthly article), but it will have the advantage of leaving the symmetry close to the surface.
Another direction is to consider $E_c$ on its own terms. It is an elliptic curve, so rational functions on it like $x,y,z$ can be parametrized by elliptic functions like $\wp$ and $\wp'$. Moreover $E_c$ inherits the $S_3$ action so the resulting formulas must retain this symmetry; and the periodicity of $\wp,\wp'$ may even cancel out the ambiguity in the arcsine or arccosine. That's great if you love elliptic curves, not so great if you regard $\wp$ as yet another obscure transcendental function... At least these elliptic curves are rather nice: the cyclic permutations of $X,Y,Z$ are translations by 3-torsion points of $E_c$, and there's also a 2-torsion point because switching two of the variables, say $Y \leftrightarrow Z$, has a rational fixed point where the third variable vanishes (this corresponds to taking $\alpha = 0$ and $\beta+\gamma=0$ in the original equation). So $E_c$ actually has 6-torsion. If I did this right, an equivalent equation for $E_c$ is
$$
y^2 = x^3 + ((c^2-3) x - (c^2-2)^2)^2,
$$
which exhibits the 3-torsion points where $x=0$, and has 2-torsion at $(x,y) = -((c^2-2)^2,0)$.
As it happens $E_c$ is not far from the universal elliptic curve with a 6-torsion point, which is given by $y^2 = x^3 + ((h-3)x - (h-2)^2)^2$. What's more, our substitution $h=c^2$ produces an elliptic K3 surface whose fiber $E_c$ becomes singular at the familiar points $c = 0, \phantom.\pm \sqrt2, \phantom.\pm \frac32$, and also $c=\infty$ — and the multiplicities at $c=0,\phantom.\pm\sqrt2,\phantom.\infty$ are large enough that this elliptic K3 surface is "extremal" (finite Mordell-Weil group, maximal Picard number)! Such surfaces have attracted considerable attention over the years, starting with the Miranda-Persson list of semistable extremal surfaces (Math. Z. 201 (1989), 339–361), which includes ours with multiplicity vector $[1,1,4,6,6,6]$. This makes your family of curves very nice in that context, even if it doesn't do much to answer your motivating question...