$\newcommand\R{\Bbb R}$If $X=S\cup T(X)$, then
$$T(X)=T(S)\cup T^2(X),\quad X=S\cup T(S)\cup T^2(X), \ldots, \\
X=S\cup T(S)\cup\cdots\cup T^{n-1}(S)\cup T^n(X) \\
\subseteq Y:=S\cup T(S)\cup\cdots\cup T^{n-1}(S)\cup T^n(\R^n).$$
On the other hand, $Y=S\cup T(Y)$, since $T^{n+1}(\R^n)=T^n(\R^n)$.
So, the largest $X$ such that $X=S\cup T(X)$ is $Y$.
In particular, if $S$ is a singleton set $\{s\}$, then the largest $X$ such that $X=S\cup T(X)$ is
$$\{s,Ts,\dots,T^{n-1}s\}\cup T^n(\R^n).$$
If e.g. $n=3$, $(e_1,e_2,e_3)$ is a basis of $\R^3$, $S=\{e_1\}$, $Te_1=e_2$, $Te_2=e_3$, and $Te_3=e_3$, then the largest $X$ such that $X=S\cup T(X)$ is
$$\{e_1,e_2\}\cup\R e_3.$$