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Today I attended a talk by Terence Tao, attended by (I'm guessing) probably at least a couple of thousand people, in which among other things he said it had been proved that no packing of spheres in three dimensions is more efficient that cubic close packing and hexagonal close packing, which are equally efficient.

My question is whether it has also been proved that no other packing is equally efficient to those two. I.e. they are the only ones that attain the greatest efficiency.

Postcript: It is being pointed out in comments that in addition to cubic close packing and hexagonal close packing, there are mixtures of the two, in which some regions of space of spheres packed "cubically" and others "hexagonally". So the question must be taken to be: do mixtures of those two exhaust the possibilities, or are there others? Has it been proved that there are no others?

Postpostscript: All right, I will be explicit about something I would have thought was obvious: Construe the question as asking whether there are any other triply periodic packings other than those two that are just as efficient as those two?

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    $\begingroup$ From Hales' unabridged proof of the Kepler conjecture: "There are uncountably many packings of [the optimal density] that have the property that every ball is tangent to twelve others and such that the tangent arrangement around each ball is either the fcc pattern or the hcp pattern." See the paper for definitions. This leaves the question of if these constitute (or if there is known) a full characterization of optimal packings. $\endgroup$
    – Mark Lewko
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    $\begingroup$ Also note that, e.g., if you remove one ball from the fcc packing, this doesn't affect the asymptotic density, so could arguably be said to be as efficient. To formulate your question more precisely you have to think about whether you want to allow such packings, and if not, what extra conditions you want to impose to exclude them. $\endgroup$ Commented Jan 5 at 21:41
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    $\begingroup$ @DanielAsimov I think "uniformly recurrent packings", as described by Greg Kuperberg in "Notions of denseness" (dx.doi.org/10.2140/gt.2000.4.277) is sort of the idea you're reaching for with "tails of packings", and it overcomes the problem of asymptotically-zero-density deformations that Peter points out. In fact, in that paper, Greg indicates (if I understand correctly) that it's likely that the only uniformly recurrent ball packings of maximum density are Barlow packings. $\endgroup$ Commented Jan 6 at 19:48
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    $\begingroup$ @MichaelHardy It may help to introduce some standard terminology. In a lattice packing, the centers of the spheres form a discrete subgroup of $\mathbb{R}^3$. A periodic packing is the union of finitely many translations of a lattice packing, and I believe that this is what you mean when you say a "triply-periodic" packing. A Barlow packing is obtained by stacking hexagonally packed layers, where at each layer you pick one of the two possibilities. $\endgroup$ Commented Jan 15 at 20:32
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    $\begingroup$ So am I correct that your question is whether every periodic packing of maximum density is a Barlow packing? Certainly there are infinitely many (and not just two) distinct Barlow packings that are periodic. $\endgroup$ Commented Jan 15 at 20:32

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The short answer is that classifying all maximum-density three-dimensional sphere packings, even the periodic ones, remains an open problem.

It will help to introduce some terminology. In a lattice packing, the centers of the spheres form a discrete subgroup of $\mathbb{R}^3$. A periodic packing is a finite union of translates of a lattice packing. As noted by other respondents, we can form uncountably many distinct maximum-density sphere packings in $\mathbb{R}^3$ by stacking hexagonally packed layers on top of each other; at each layer, we have two choices, so such packings, which are called Barlow packings, are indexed by bi-infinite sequences on three letters such that consecutive letters are distinct.

The title question asks if it is possible that there are just two maximum-density packings. I cannot think of any interpretation of this question under which the answer is yes. If we restrict to maximum-density lattice packings, then the face-centered cubic packing is the only lattice packing (the hexagonal close packing is periodic but it is not a lattice packing). If we require only that the packing be periodic, then there are infinitely many periodic Barlow packings (though of course, not every Barlow packing is periodic).

Again, as others have noted, if we allow non-periodic packings, then there are all kinds of packings that can achieve maximum density. But we could ask, is every maximum-density periodic packing a Barlow packing? This type of question is potentially tractable; for example, Viazovska's work actually shows that $E_8$ is the unique periodic packing in $\mathbb{R}^8$ of maximum density. However, as far as I can tell, even this question remains open in three dimensions. A standard reference is Conway and Sloane, What are all the best sphere packings in low dimensions?, Discrete Comput. Geom. 13 (1995), 383–403. Among other things, they propose a definition of a "tight" packing and show that, subject to two unproved postulates, the Barlow packings are the only tight packings. At the time of Conway and Sloane's paper, of course, the Kepler conjecture was still open, but when Hales announced his proof in An overview of the Kepler conjecture, he pointed out that Conway and Sloane's problem of characterizing the tight packings in $\mathbb{R}^3$ was still open.

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    $\begingroup$ What do you think about: "the CCP and HCP are the only dense sphere packings whose symmetry group acts transitively on the spheres"; is that known to be true/false? $\endgroup$ Commented Jan 16 at 22:06
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    $\begingroup$ @SamHopkins Ah, that would be a plausible question whose answer might be 2. In Conway and Sloane's paper, they call such a thing a uniform packing. The argument in their paper might settle this question given that the Kepler conjecture is now settled, but I'm not 100% sure. $\endgroup$ Commented Jan 16 at 22:17
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    $\begingroup$ Also in the mentioned paper "Notions of denseness" by Kuperberg (arxiv.org/abs/math/9908003), in the last section he seems to suggest something is wrong with the "tightness" notion from Conway and Sloane, though reading quickly I don't totally grasp what the issue is. $\endgroup$ Commented Jan 16 at 23:08
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    $\begingroup$ @SamHopkins - My old paper on this has a counterexample in Figure 6. What should be the optimal circle packing in 2 dimensions isn't "tight" in the sense of Conway and Sloane. Their game with rearrangements of pieces of the plane creates an illusion that the packing has wasted space that can be eliminated. But the "wasted" space isn't actually eliminated, it is carried off to infinity. $\endgroup$ Commented Feb 14 at 7:57
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I am posting this as a community wiki post because I am just reiterating things said in the comments, but I think you are missing some basic points and so wanted to highlight those.

You should read the Wikipedia article Close-packing of equal spheres.

In particular, you should look at this image from that Wikipedia page: enter image description here It explains how to iteratively create a close packing of spheres (one attaining the maximum density) in layers. In the first step, we follow the "A" pattern, in the second step, we follow the "B" pattern, and then in the 3rd step we have a choice of either "A" or "C" pattern. We can continue in this way as long as at each step we choose a different letter than the one we are at. So different sequences of A's, B's, C's give different packings.

The cubic close packing corresponds to the pattern ABC ABC ABC ..., while the hexagonal close packing corresponds to the pattern AB AB AB .... Taking some other pattern, but which still is periodic, like say ABC AB ABC AB ..., will give another close packing of spheres which is not either of those two, but which is still "triply periodic" in the sense of your postpostscript. So the literal answer to the question in your postpostscript is: no, there are other packings beyond those two which are triply periodic and just as efficient.

EDIT: Packings of these kind are called Barlow packings. As suggested in the comments, perhaps your question ought to be whether all periodic packings of maximum density are Barlow packings. I am fairly certain this must be an open question. Again, referencing something brought up in the comments, in Kuperberg's "Notions of denseness", he says "It seems likely that a sphere packing is weakly recurrent among dense packings if and only if it is Barlow, but not all Barlow packings are uniformly recurrent." Here "weakly recurrent" and "uniformly recurrent" are technical notions having to deal with the issue of asymptotically-zero-density deformations, but morally they should be similar to periodic.

On the other hand, if maybe your interest is instead to single out the cubic close packing and hexagonal close packing among all maximally dense sphere packings, then you may be interested in this quote from "Recent Progress in Sphere Packing" by Conway, Goodman-Strauss, and Sloane: "Only two of these [Barlow packings] are 'uniform,' however, in the sense that there is a symmetry of the packing taking any one sphere to any other." So possibly that could be a characterization: the CCP and HCP are the only maximally dense sphere packings where the symmetry group acts transitively on the spheres. I am not sure if that is known.

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