$O_K^\times$ is compact thus so is $$K^\times/ \pi_F^\Bbb{Z}=\pi_K^{\Bbb{Z/eZ}} \times O_K^\times, \qquad e=\frac{v(\pi_F)}{v(\pi_K)}$$ Being a quotient of a compact group by a closed subgroup $$K^\times/F^\times=(K^\times/ \pi_F^\Bbb{Z})/(F^\times/ \pi_F^\Bbb{Z})$$ is compact.
Otherwise you can use the isomorphism $\log : 1+ p^2 O_K\to p^2 O_K$ to make it more concrete, as $(1+p^2 O_K)/(1+p^2O_F)$ is a finite index subgroup of $O_K^\times /O_F^\times$ and $K^\times/F^\times$.
The structure theorem is that $O_K^\times / (O_K^\times)_{tors}$ is a torsion free $\Bbb{Z}_p$ module with $1+p^2O_K$ as a finite index subgroup, thus isomorphic to $O_K$, so that $K^\times \cong \pi_K^\Bbb{Z} \times (O_K^\times)_{tors}\times O_K$
The torsion of $H=(O_K^\times / (O_K^\times)_{tors})/(O_F^\times / (O_F^\times)_{tors})$ is not obvious, as it is non-trivial for $\Bbb{Q}_3((1+3)^{1/3})/\Bbb{Q}_3$, and $$K^\times/F^\times \cong \pi_K^{\Bbb{Z/eZ}} \times (O_K^\times)_{tors}/(O_F^\times)_{tors} \times H\times O_K/O_F$$