Let $\mathcal{C}$ be an $\infty$-category, and let $u:x\rightarrow y$ be an edge. It seems reasonable to say that: The map $Map_{\mathbb{C}[\mathcal{C}]}(a,x)\rightarrow Map_{\mathbb{C}[\mathcal{C}]}(a,y)$ given by composition with $u\in Map_{\mathbb{C}[\mathcal{C}]}(x,y)_0$, where $\mathbb{C}[\mathcal{C}]$ is the simplical category associated to $\mathcal{C}$, is equivalent in the homotopy category of simplicial sets to the composite $\mathcal{C}_{\backslash x}\times_{\mathcal{C}}\{a\}\rightarrow \mathcal{C}_{\backslash u}\times_{\mathcal{C}}\{a\} \rightarrow \mathcal{C}_{\backslash y}\times_{\mathcal{C}}\{a\}$, where the first map is a section of the trivial fibration $\mathcal{C}_{\backslash x}\times_{\mathcal{C}}\{a\}\leftarrow \mathcal{C}_{\backslash u}\times_{\mathcal{C}}\{a\}$.
However, I am unable to come up with a proof, and have not found one in HTT. I would guess that one needs to use the straightening functor, as is done to identify the targets, but how to deal with the composition map of the simplicial category associated to $\mathcal{C}$?
EDIT: I am relatively convinced that it boils down to proving that the maps: $$(St_{\mathcal{C}}\mathcal{C}_{/f})(a)\rightarrow (St_{\mathcal{C}}\mathcal{C}_{/x})(a)\rightarrow Map_{\mathbb{C}[\mathcal{C}]}(a,x)\rightarrow Map_{\mathbb{C}[\mathcal{C}]}(a,y)$$ and $$(St_{\mathcal{C}}\mathcal{C}_{/f})(a)\rightarrow (St_{\mathcal{C}}\mathcal{C}_{/y})(a)\rightarrow Map_{\mathbb{C}[\mathcal{C}]}(a,y)$$ are homotopic, where $(St_{\mathcal{C}}\mathcal{C}_{/x})(a)\rightarrow Map_{\mathbb{C}[\mathcal{C}]}(a,x)$ corresponds to the map $f''$ in HTT 2.2.4 but I do not see any reasonnable way to proceed.