Yes. Take the Levi-Civita connection of any conformal metric $g = e^{2u}(dx^2+dy^2)$ of positive curvature, say. Then, by (local) Gauss-Bonnet, the holonomy around any smooth closed loop $\gamma$ is of the above form with $a = \cos\theta(\gamma)$ and $b=\sin\theta(\gamma)$, where
$$
\theta(\gamma) = \int_{\mathbb{R}^2\setminus\mathrm{Im}\,\gamma} \nu_\gamma\,K\,dA,
$$
where $\nu_{\gamma}:\mathbb{R}^2\setminus\mathrm{Im}\,\gamma\to\mathbb{Z}$ gives the winding number of $\gamma$ about the points of $\mathbb{R}^2$ that do not lie on the image of $\gamma$. When $\gamma_r$ is the circle $(r\cos\phi,r\sin\phi)$ for $r>0$, $\theta(\gamma_r)$ is just the total curvature of the metric contained in the interior of the disk. Since $K>0$, this number increases as $r$ increases.