For any prime number $p$ we can define a Cayley graph with integer vertices and edges:
\begin{eqnarray} V &=& \mathbb{Z}/p\mathbb{Z} \\ E &=& \{ (x, x\pm 1), (x, x \pm 2) : x \in V \} \end{eqnarray}
What is the spectrum of this graph? I think that is an easy one. Then I would like to add one edge: $$ E' = E \cup \bigg\{ \big(0\;,\; 0 + \tfrac{p+1}{2}\big) \bigg\} $$
How does the spectrum of my new graph change with respect to the old ones?
If I write out the matrix I think I get (here for $p = 5$) in general a band matrix and even a Toeplitz matrix
$$ \left[ \begin{array}{ccccc} 0 & 1 & 1 & 1 & 1 \\ 1 & 0 & 1 & 1 & 1 \\ 1 & 1 & 0 & 1 & 1 \\ 1 & 1 & 1 & 0 & 1 \\ 1 & 1 & 1 & 1 & 0 \end{array} \right]$$ Or even better we could just define the transfer operator (arithmetic taken mod $p$): $$ f(x) \stackrel{T}{\mapsto} \frac{f(x+1)+ f(x+2)+f(x-1)+f(x-2)}{4} $$ I don't immediately recall the eigenvalues but they were quite explicit.
I believe spectrum is the set of roots of unity $\lambda \in \{ = e^{2\pi i \, \frac{k}{p}}: 0 \leq k < p-1 \}$ but the eigenvectors change with the choice of generators (in our case $\pm1, \pm 2$).
These notes say I have defined $C\big(\mathbb{Z}/p\mathbb{Z}, (1,2)\big)$ but I could have used any generators. And the eigenvalues are all real.
We can predict how the eigenvalues change when we add the single edge: $\big(0, \frac{1}{2}(p-1)\big)$ e.g. using Hadamard's variation formulas how much does it move?