The invention of intrinsic differential geometry is usually attributed to Gauss in the context of his theorema egregium but the notion of the curvature of an embedded surface existed before. Who was the first to discover that the curvature of an embedded surface is the product of the principal curvatures?
In http://arxiv.org/abs/1409.4736 the author states: "In 1763, Euler started a thorough study of curvature of embedded surfaces. In 1767, he found an expression of the curvature in terms of the product of principal curvatures."
This seems to suggest that the curvature Euler is talking about is what is known today as Gaussian curvature, the latter being the product of principal curvatures. However, this comment in 1409.4736 seems to be based on a different comment in the 2008 encyclopedia of scientific biography at http://www.encyclopedia.com/topic/Johann_Tobias_Mayer.aspx#1-1G2:2830901353-full which states:
"In 1763 Euler made the first substantial advance in the study of the curvature of surfaces; in particular, he expressed the curvature of an arbitrary normal section by principal curvatures (1767)."
This of course does not imply any relation to Gaussian curvature and on the contrary suggests that Euler only dealt with curvatures of curves obtained as cross-sections of the embedded surface. However, it is possible that 1409.4736 has a different source for this claim.
The relevant paper by Euler is apparently http://eulerarchive.maa.org/docs/originals/E333.pdf where on page 143 Euler discusses the two radii of curvature.