I am following these lecture notes:
Given the i.i.d. $\mathcal{Z}$-valued random variables $Z_1,\dotsc,Z_m$ and $\mathcal{G}$ is a set of bounded functions $g\colon \mathcal{Z}\to[a,b]$.
Corollary 2.3 says:
With probability at least $1-\delta$, $$ \sup_{g\in\mathcal{G}} \left( \mathbb{E}[g(Z)]-\frac{1}{m}\sum_{i=1}^mg(Z_i) \right) \leq 2\mathfrak{R}_m(\mathcal{G})+(b-a)\sqrt{\frac{\ln(1/\delta)}{2m}} $$
where $\mathfrak{R}_m(\mathcal{G})$ is the Rademacher average:
Let $\epsilon_1,\dotsc,\epsilon_m$ be i.i.d. $\{\pm\}$-valued random variables with $\mathbb{P}(\epsilon_i = +1)=\mathbb{P}(\epsilon_i = -1)=1/2$. These are also independent of the sample $Z_1,\dotsc,Z_m$. Define the empirical Rademacher average of $\mathcal{G}$ as
$$ \hat{\mathfrak{R}}_m(\mathcal{G}) = \mathbb{E}\left[ \sup_{g\in\mathcal{G}} \frac{1}{m} \sum_{i=1}^m \epsilon_i g(Z_i) \Bigg\vert Z_1^m \right]. $$
The Rademacher average of $\mathcal{G}$ is defined as
$$ \mathfrak{R}_m(\mathcal{G}) = \mathbb{E}\left[ \hat{\mathfrak{R}}_m(\mathcal{G}) \right]. $$
From Corollary 2.3 using $\epsilon = 2 \mathfrak{R}_m(\mathcal{G})+(b-a)\sqrt{\frac{\ln(1/\delta)}{2m}}$ it follows
\begin{align} \mathbb{P}\left(\sup_{g\in\mathcal{G}} \left( \mathbb{E}[g(Z)]-\frac{1}{m}\sum_{i=1}^mg(Z_i) \right) \geq\epsilon\right) \leq \exp\left(-\frac{2m(\epsilon-2\mathfrak{R}_m(\mathcal{G}))^2}{(b-a)^2} \right) \quad \quad (1) \end{align}
I try to compare this to Hoeffding's Inequality for real valued random variables. Therefore assume that $Z_1,\dotsc,Z_m$ are real-valued random variables with $\mathbb{P}(Z_i\in[a,b]) = 1$, and let $g$ be the identity function and $\mathcal{G} = \{g\}$.
Then $(1)$ becomes
\begin{align} \mathbb{P}\left( \mathbb{E}[Z]-\frac{1}{m}\sum_{i=1}^mZ_i \geq\epsilon\right) \leq \exp\left(-\frac{2m(\epsilon-2\mathfrak{R}_m(\mathcal{G}))^2}{(b-a)^2} \right) \end{align} which seems to be an improvement over Hoeffding's Inequality whenever $\mathfrak{R}_m(\mathcal{G}) > \epsilon$.
Is there a way to tell $\mathfrak{R}_m(\mathcal{G}) \leq \epsilon$ or is this a better bound than the one of Hoeffding?
Edit:
My question seems to be more fundamental: Let $$ S: {Z}^m \mapsto \left\lVert\frac{1}{m}\sum_{i=1}^mZ_i - \mathbb{E} \left[\frac{1}{m}\sum_{i=1}^m Z_i\right]\right\rVert. $$ Then $S$ fulfills the bounded difference property with $c = \frac{(b-a)}{m}$ e.g. $$ \sup_{Z_i'\in\mathcal{Z}} | S(Z_1,\dots,Z_i,\dots,Z_m) - S(Z_1,\dots,Z_i',\dots,Z_m) | \leq c $$ and hence with $v=\frac{mc^2}{4}$ \begin{align} \mathbb{P}\left(S-\mathbb{E}[S] \geq t \right) \leq \exp\left( -\frac{t^2}{2v} \right) \end{align} for $t> 0$. Using $\epsilon = t + \mathbb{E}[S]$ we get \begin{align} \mathbb{P}\left(S \geq \epsilon \right) &\leq \exp\left( -\frac{(\epsilon-\mathbb{E}[S])^2}{2v} \right) \\ \mathbb{P}\left(\left\lVert\frac{1}{m}\sum_{i=1}^mZ_i - \mathbb{E} \left[\frac{1}{m}\sum_{i=1}^m Z_i\right]\right\rVert \geq \epsilon \right) &\leq \exp\left( -\frac{2m(\epsilon-\mathbb{E}[S])^2}{(b-a)^2} \right) \end{align} The Rademacher average was only used to upper bound $\mathbb{E}[S]$ on the RHS.
I again, compare this to Hoeffding's or Azuma's Inequality and wonder which one to use. Is there anything that can be said about the behaviour of $\mathbb{E}[S]$?