Recall that a symplectic groupoid (http://projecteuclid.org/euclid.bams/1183553676) is a Lie groupoid $\mathcal{G}\rightrightarrows X$ together with a symplectic structure on $\mathcal{G}$ multiplicative with respect to the groupoid multilpication and such that the unit map $X\rightarrow \mathcal{G}$ is Lagrangian.
It is known that some Poisson manifolds $X$ can be integrated to symplectic groupoids $\mathcal{G}\rightrightarrows X$. Conversely, given a symplectic groupoid $\mathcal{G}\rightrightarrows X$ one can uniquely recover a Poisson structure on $X$ such that $p_1\colon\mathcal{G}\rightarrow X$ is Poisson and $p_2\colon\mathcal{G}\rightarrow X$ is anti-Poisson.
What is an object integrating a Poisson-Lie group $G$?
Clearly, this should give rise to a symplectic groupoid $\mathcal{G}\rightrightarrows G$ together with three Lagrangians in $\mathcal{G}\times\mathcal{G}\times\overline{\mathcal{G}}$ (here bar means the manifold with the opposite symplectic structure) lifting the two projections and the multiplication, and a Lagrangian $\mathcal{G}\times_G\mathcal{G}\rightarrow \mathcal{G}\times\mathcal{G}\times\overline{\mathcal{G}}$ from the definition of a symplectic groupoid.
I would guess that the corresponding object should be a symplectic 2-groupoid $\mathcal{G}_2\stackrel{\rightarrow}\rightrightarrows G\rightrightarrows \mathrm{pt}$, but I haven't figured out how to get the 4 Lagrangians.
Note that there is a known integration of doubles of Poisson groups to double symplectic groupoids and hence to symplectic 2-groupoids (http://arxiv.org/abs/1012.4103), but the one-simplices of the latter are something like $G\times G^\ast$ instead of just $G$.