Edite According to the essential comment of Ian Agol I revise the question as follows
For a smooth manifold $M$, is there a non identity involution $\theta$ on the lie algebra $\chi^{\infty}(M)$ such that $X$ is topological equivalent to $\theta (X)$, for all smooth vec. field $X$ on $M$?
This question is motivated by the fact that, on $\mathbb{R}^{n}$ the linear vector field $\dot X=AX$ is topological equivalent to the linear vector field $\dot X=-A^{tr}X$.
By topological equivalent, we mean existence of an orbit preserving homeomorphism.