If one has a nonstandard model $\mathcal{N}$ of PA and adjoins to the first-order theory the countable list of axioms $1<H,\, 2<H,\, 3<H, \ldots$ (satisfied in $\mathcal{N}$) for all the "standard" natural numbers, an application of downward Lowenheim-Skolem theorem should yield a countable nonstandard model $\mathcal{N}'$ of PA (such as the one described by Skolem in 1933/34).
If one wants to get more of the structure available in Skolem's model, such as transfer for all definable functions, how would one do this exactly using downward L-S? Joel David made some suggestions in this direction in his "comments" below, and I am interested in a possible reference that may fill in some of the details.
More specifically, in Robinson's framework $(\mathbb{R}, {}^{\ast}\mathbb{R}, \ast)$, each hyperinteger $H$ can be included in a countable substructure elementarily equivalent to the Skolem model. What is the strongest sense in which one can take the word "equivalent" here?