The Bloch-Wigner function $D(z)$ gives the volume of an ideal tetrahedron in the hyperbolic space $\mathbb{H}^3$. Here $z$ is the cross-ratio $(z_1,z_2,z_3,z_4)$ parametrizing the tetrahedron in $\mathbb{C}P^1$.
Put $\tilde D(z_1,z_2,z_3,z_4) = D(z)$.
The five-term relation for the dilogarithm could be interpreted as the fact that the signed sum of some volumes of tetrahedra vanishes:
$$\sum^4_{i=0} (-1)^i \tilde D(z_0, ...., \hat z_i, ... z_4) = 0$$
Here the $z_i$ are 5 points in $\mathbb{C}P^1$, and the notation $\hat z_i$ means that we don't take the vertex $z_i$ in account. The above equation looks like some function of a boundary of some 5-simplex.
But what is this 5-simplex (which, I think, corresponds to a 4-volume), and in what space this simplex exists (hyperbolic space ?) ?
Reference (Zagier) : http://maths.dur.ac.uk/~dma0hg/dilog.pdf (Pages 10 - 11)