A couple of recent questions on MO have involved the characters or the orders of specific finite groups of the form $G(\mathbb{Z}/n\mathbb{Z})$ for a familiar algebraic group $G$ defined over $\mathbb{Z}$ (implicitly as a group scheme) especially when $n$ is a prime power: here and here.
It's reasonable to ask in what generality questions of the second kind can be treated uniformly. Here for example the question doesn't seem to require any knowledge of the structure of symplectic matrices, once one knows the orders of the finite symplectic groups over fields. (These have been written down in numerous papers and books.) In particular:
For group schemes $G$ over $\mathbb{Z}$, in what natural generality is there a uniform procedure for computation of the orders of finite groups $G(\mathbb{Z}/p^k\mathbb{Z})$ as $p$ ranges over the prime numbrs?
An old computation having a similar flavor occurs for the multiplicative group scheme (which is reductive but not simple) in the determination of the group of units in the ring $\mathbb{Z}_p$ of $p$-adic integers, written as an inverse limit of finite groups with successive quotients of order $p-1$ or $p$. Here the additive group scheme (viewed as the Lie algebra of the multiplicative group scheme) enters the picture, providing an iterated extension of the group of units of the residue field $\mathbb{F}_p$. See for example the book by Serre A Course in Arithmetic, II, section 3.
As George McNinch points out in his comment on Scott Carnahan's direct computation of the order for finite symplectic groups, a uniform approach is suggested by a paper of Serre, "Exemples de plongements des groupes PSL$_2(\mathbb{F}_p)$ dans des groupes de Lie simples", Invent. Math. 124 (1996), 3.1. Here G is a connected simple algebraic group over an algebraically closed field, essentially treated as a group scheme. Serre refers in turn to Demazure-Gabriel, Groupes Algebriques (1970), II, section 4, no. 3, a treatise influenced by the earlier Demazure-Grothendieck seminar SGA3.
In a Bourbaki talk, Chevalley showed how to view the simple adjoint groups, which he had constructed in a uniform way in 1955, as group schemes over $\mathbb{Z}$, a theme refined further by Kostant, and more recently by Lusztig in J. Amer. Math. Soc. 22 (2009). That seems to be a good setting for the question I've raised, though perhaps one can go further in the direction of reductive groups?
ADDED: The answers and comments are very interesting, but while I think further about them and the literature I should clarify that I'm taking for granted the standard (though nontrivial) formulas for the group orders over finite fields. And while it's natural (at least for Chevalley groups) to start over the ring of integers, there is certainly a passage to local rings implied here. The specific prime stays in the background, since unlike many questions in Lie theory this kind of computation doesn't distinguish "good" and "bad" primes: whatever is done should apply uniformly to all primes. Meanwhile a result in Appendix A.5 of the recent book by Conrad-Gabber-Prasad on pseudo-reductive groups has been pointed out to me. This suggests that groups aren't so essential to my question, but only a well-behaved class of schemes (again assuming that one can already count their points over finite fields).