Ramanujan gave the value $$\frac{1}{\sqrt{Q_n}}\left(\sqrt{n}P_n-\frac{6}{\pi}\right)=\sqrt{2}\tag{1}$$ for $n=11$ and I have now completed the calculations needed to prove this using an approach suggested at the end of the question.
We need two ingredients here with the first one being the modular equation of degree $11$ given by Ramanujan $$\sqrt{kl} +\sqrt{k'l'} +2(4klk'l')^{1/6}=1\tag{1}$$ The equation is symmetric in $k, l$ and hence works when modulus $l$ is of degree $11$ over modulus $k$ as well as when $k$ is of degree $11$ over $l$. Let us assume the latter here and let $k, l$ correspond to nomes $e^{-\pi\sqrt{11}},e^{-\pi/\sqrt{11}} $ respectively so that $l=k'$ and then the equation $(1)$ reduces to $$2\sqrt{kk'}+2(2kk')^{1/3}=1$$ Let us further observe that $G=G_{11}=(2kk')^{-1/12}$ and hence the above equation can be written in terms of $G$ as $$2(G^{-12}/2)^{1/2}+2G^{-4}=1$$ or $$\sqrt{2}+2G^{2}=G^6$$ so that $a=G^2=G_{11}^2$ is the root of $$f(x) = x^3-2x-\sqrt{2}\tag{2}$$ It can be checked that this equation has no roots in $\mathbb{Q} (\sqrt{2})$ and hence $a$ is of degree $3$ over $\mathbb{Q} (\sqrt{2})$ and hence of degree $6$ over $\mathbb{Q} $.
The minimal polynomial for $a$ over rationals is then $$(x^3-2x-\sqrt{2})(x^3-2x+\sqrt{2})$$ or $$x^6-4x^4+4x^2-2$$ so that $b=a^2=G_{11}^4$ is a root of $$g(x) =x^3-4x^2+4x-2\tag{3}$$ Next ingredient we need is the expression for $nP(q^{2n})-P(q^2)$ for $n=11$ provided by Ramanujan as $$nP(q^{2n})-P(q^2)=\frac{8KL}{\pi^2}\left\{2(1+kl+k'l')+\sqrt{kl} +\sqrt{k'l'} - \sqrt{klk'l'} \right\}\tag{4}$$ and here we can again assume $k$ being of degree $11$ over $l$ so that $l$ corresponds to $q$ and $k$ to $q^{n} $ and $K'/K=nL'/L$. Putting $q=e^{-\pi/\sqrt{11}}$ so that $l=k'$ and $L/K=K'/K=\sqrt {11}$ we get $$nP(q^{2n})-P(q^2)=\sqrt{11}\left(\frac{2K}{\pi}\right)^2(4(1+2kk')+4\sqrt{kk'}-2kk')$$ or $$nP(q^{2n})-P(q^2)=\sqrt{11}\left(\frac{2K}{\pi}\right)^2(4(1+G^{-12})+2\sqrt{2}G^{-6}-G^{-12})$$ or $$nP(q^{2n})-P(q^2)=\sqrt{11}\left(\frac{2K}{\pi}\right)^2(4+3b^{-3}+2\sqrt{2}a^{-3})$$ Using $\sqrt{2}=a^3-2a$ we get $$nP(q^{2n})-P(q^2)=\sqrt{11}\left(\frac{2K}{\pi}\right)^2\frac{6b^3-4b^2+3}{b^3}$$
We need another identity $$nP(q^{2n})+P(q^2)=\frac{6\sqrt{n}}{\pi}$$ which holds for $q=e^{-\pi/\sqrt{n}} $. Using this identity together with previous equation we get $$2P(e^{-2\pi\sqrt {11}})=\frac{6}{\pi\sqrt{11}}+\frac{1}{\sqrt{11}} \left(\frac{2K}{\pi}\right)^2\frac{6b^3-4b^2+3}{b^3}\tag{5}$$ Next we use the identity $$2P(q^2)-P(-q)=\left(\frac{2K}{\pi}\right)^2(1-2k^2)$$ with $q=e^{-\pi\sqrt{11}}$ to get $$P(-q)=\frac{6}{\pi\sqrt{11}}+\left(\frac {2K}{\pi}\right)^2\left(\frac{6b^3-4b^2+3}{b^3\sqrt{11}}-(1-2k^2)\right)$$ or $$\sqrt{n} P_n-\frac{6}{\pi}=\left(\frac {2K}{\pi}\right)^2\left(\frac{6b^3-4b^2+3}{b^3}-\frac{\sqrt{11(b^6-1)}}{b^3}\right)\tag{5}$$ as $$(1-2k^2)^2=1-G^{-24}=1-b^{-6}$$ To evaluate $Q_n$ we note that $$Q(-q) =\left(\frac{2K}{\pi}\right) ^4(1-4G^{-24})=\left(\frac{2K}{\pi}\right) ^4\frac{b^6-4}{b^6}$$ and hence $$\frac{1}{\sqrt{Q_n}}\left(\sqrt{n}P_n-\frac{6}{\pi}\right)=\frac{6b^3-4b^2+3-\sqrt{11(b^6-1)}}{\sqrt {b^6-4}}$$ The expression on right simplifies to $\sqrt{2}$ in a miraculous manner as demonstrated in this answer of mine.
A similar calculation can be done for $n=19$ by noting that $2^{1/4}G_{19}$ is the real root of $x^3-2x-2$ and $$nP(q^{2n})-P(q^2)=\frac{24KL}{\pi^2}\left\{1+kl+k'l'+\sqrt{kl}+\sqrt{k'l'}-\sqrt {klk'l'} \right\}$$ and we can verify that $$\frac{1}{\sqrt{Q_n}}\left(\sqrt{n} P_n-\frac{6}{\pi}\right)=\sqrt{6}$$ for $n=19$. Using similar formulas given by Ramanujan we can verify the values for $n= 27, 35$, but for other values of $n$ there are no known formulas of similar kind to help us.
More generally if there is a formula of type $$nP(q^{2n})-P(q^2)=\frac {4KL}{\pi^2} \cdot A_n(k, l) $$ then $$\frac{1}{\sqrt{Q_n}}\left(\sqrt{n} P_n-\frac{6}{\pi}\right)=\frac{G_n^{12}\cdot A_n(k, k') - \sqrt {n(G_n^{24}-1)}} {\sqrt{G_n^{24}-4} } $$ Ramanujan also gave formulas of type $$nP(-q^n) - P(-q) =\frac{4KL}{\pi^2}\cdot B_n(k,l)$$ for some odd positive integer values of $n$ and if such a formula is available then $$\frac{1}{\sqrt{Q_n}}\left(\sqrt{n} P_n-\frac{6}{\pi}\right)=\frac{G_n^{12}\cdot B_n(k, k') } {2\sqrt {G_n^{24}-4} }$$
There is an empirical approach which works nicely for $n=11,19,43,67,163$. If we evaluate the expression $$\frac{1}{\sqrt{Q_n}}\left(\sqrt{n} P_n-\frac{6}{\pi}\right)$$ for $n=11,19$ then it is easy to spot that these values are $\sqrt{2},\sqrt{6}$ respectively.
Next for each of the values of $n$ mentioned in last paragraph one can prove that $G_n^8$ is a root of a polynomial $$x^3-a_nx^2-4$$ where $a_n$ is a positive integer. Further we can write $a_n=b_n^2\cdot c_n$ where $c_n$ is square free so that $$\sqrt{G_n^{24}-4}=\sqrt{x^3-4}=b_n x\sqrt{c_n}, x=G_n^8$$ and we can evaluate the expression $$\sqrt{\frac{c_n}{Q_n}}\left(\sqrt{n} P_n-\frac{6}{\pi}\right)$$ numerically and confirm that it is an almost integer (depending on precision of numerical calculation) and let us say that the nearest integer is $d_n$. Then the expression in question is $d_n/\sqrt{c_n} $. Moreover for $n=43,67,163$ the expressions $P_n, Q_n$ are practically equal to $1$ and hence one just needs to evaluate the much simpler expression $$\sqrt{c_n} \left(\sqrt{n} - \frac{6}{\pi}\right)$$ and it turns out to be an almost integer. For completeness sake let us note that $c_n$ equals $2,6,15, 330,10005$ for $n=11,19,43,67,163$ respectively.
Having guessed the value of the expression under question empirically we can then try to prove it using approach discussed in first part of the answer.