It is a well-known exercise that $C_n = \chi_{(n,n)}(1)=\chi_{(n,n)}^{1^n}$ where $C_n$ is the $n$th Catalan number and $\chi_{(n,n)}^{1^n}$ is the character of the irrep $(n,n)$ on conjugacy class $1^n = (1,1,\cdots,1)$.
A related identity that I stumbled across for fixed-point-free involutions is that $\chi_{(n,n)}^{2^n} = \pm \binom{n}{\lfloor n/2 \rfloor}$.
I haven't been able to find this stated as an exercise in a textbook or online manuscript, and it seems too obvious to have been overlooked. If you have seen this identity before and recall the reference, I would be happy to know.