Connected and complete maximally symmetric spaces have constant curvature and therefore are space forms. It is fairly easy to prove that simply connected space forms are completely characterized by their index, curvature, and dimension (see Chapter 8, proposition 23 in O'Neill Semiriemannian Geometry).
The simply connected space forms can be presented all as generalisations of Euclidean, hyperbolic, and spherical spaces in the following way (Chapter 8, Corollary 24, Ibid):
- Euclidean $\implies$ Flat semi-Riemannian spaces of some index, including of course Minkowski spaces.
- Sphere $\implies$ pseudo-spheres. For index $(j,k)$ (which I take to mean dimension $j+k$ and $j$ minuses and $k$ pluses), this is (the universal cover of a component of) the set $\{|x| = c^2\}$ in $\mathbb{R}^{j,k+1}$.
- Hyperbolic $\implies$ pseudo-hyperbolic spacess. For index $(j,k)$ this is (the universal cover of a component of) the set $\{|x| = -c^2\}$ in $\mathbb{R}^{j+1,k}$.
By a covering argument all connected components of space-forms are quotients of these three guys. (For example, in 3 dimension, Riemannian case, don't forget the lens spaces.) For this you should remember that the symmetry groups are
- pseudo-Euclidean spaces $\mathbb{R}^{j,k}$ has symmetry group $\mathbb{R}^{j,k} \rtimes SO(j,k)$
- pseudo-spheres have the Lorentz group of the ambient space $SO(j,k+1)$
- pseudo-hyperbolic spaces have the Lorentz group of the ambient space $SO(j+1,k)$.