Let X be a deminormal variety (over Char 0). Then is it true that the dualizing sheaf is divisorial?
Please provide a reference..
It is. In any characteristic. It is torsion-free and $S_2$ on any excellent scheme. On a demi-normal scheme it is free in codimension $1$, so it is reflexive by [Stacks Project, Tag 0AVB] and hence it is a rank $1$ reflexive sheaf.