Let $\Gamma< PSL(2,\mathbb R)$ (not $SL(2,\mathbb R$)!) be a cocompact Fuchsian group. Given a Lie group $G$ one defines
- The representation variety $R(\Gamma, G)=Hom(\Gamma,G)$. One further defines $R_0(\Gamma,G)\subset R(\Gamma,G)$
as the (open) subset consisting of homomorphisms $\rho$ such that the coadjoint representation $Ad^*\circ \rho$ of $\Gamma$ on the dual space of the Lie algebra ${\mathfrak g}$ of $G$ has no fixed vectors. (In the case $G=SU(n)$ this is a weaker assumption than irreducibility that you want to impose.)
If $G$ is compact (more generally, reductive), there is a natural invariant nondegenerate bilinear form on ${\mathfrak g}$ making coadjoint representation isomorphic to the adjoint representation. If $G$ is compact, one defines further quotients
$$
X_0(\Gamma, G)\subset X(\Gamma,G)
$$
obtained by taking quotients of $R(\Gamma, G), R_0(\Gamma, G)$ by the action of inner automorphism group of $G$. Informally, these are known as character varieties. (An algebraic geometer would object, but you are a physicist, so you would not care about this terminological abuse.)
Theorem. If $G$ is a Lie group, then $R_0(\Gamma, G)$ is a smooth manifold. (Ok, another terminological abuse here.)
If $G$ is a compact Lie group then $X_0(\Gamma, G)$ is a smooth manifold as well.
You can find a proof in
Weil, André, Remarks on the cohomology of groups, Ann. Math. (2) 80, 149-157 (1964). ZBL0192.12802.
- Regarding the symplectic structure. Let $\pi$ denote the fundamental group of a compact surface with boundary $S$, with $n$ oriented boundary circles $c_1,...,c_n$; I will identify these loops with corresponding elements $c_1,...,c_n\in \pi$ (well-defined up to conjugation). Let $G$ be a Lie group and $C_1,...,C_n$ are conjugacy classes in $G$. Given this, one defines the relative representation variety
$$
R(\pi, G; C_1,...,C_n)=\{\rho\in Hom(\pi, G) | \rho(c_i)\in C_i, i=1,...,n\}.
$$
Similarly, one defines $R_0(\pi, G; C_1,...,C_n)$ and, assuming $G$ is compact, one also defines relative character varieties:
$$
X_0(\pi, G; C_1,...,C_n)\subset X(\Gamma,G; C_1,...,C_n).
$$
Weil's theorem applies to these as well. It turns out that relative character varieties also have natural symplectic structures, see for instance
Jeffrey, Lisa C., Symplectic forms on moduli spaces of flat connections on 2-manifolds, Kazez, William H. (ed.), Geometric topology. 1993 Georgia international topology conference, August 2–13, 1993, Athens, GA, USA. Providence, RI: American Mathematical Society. AMS/IP Stud. Adv. Math. 2(pt.1), 268-281 (1997). ZBL0904.57009.
One similarly defines relative character varieties if each $C_i$ is a finite union of conjugacy classes, these are just disjoint unions of relative character varieties defined above. How does this relate to Fuchsian groups? Each cocompact Fuchsian group $\Gamma$ has a presentation where one starts with a group $\pi$ as above and adds relators $c_i^{p_i}=1$, $i=1,...,n$. Now, given a Lie group $G$, define finite unions of conjugacy classes in $G$, $C_1,...,C_n$, where $C_i$ consists of all elements of (finite) order dividing $p_i$. Then, assuming that $G$ is compact,
we obtain natural isomorphisms (in any sense of the word)
$$
R(\pi, G; C_1,...,C_n)\cong R(\Gamma, G),..., X_0(\pi, G; C_1,...,C_n)\cong X_0(\Gamma, G).
$$
Thus, Jeffrey's symplectic form yields a symplectic form (of finite volume) on $X_0(\Gamma, G)$.
Many other things are known about geometry and topology of $X(\pi, G; C_1,...,C_n)$ and, hence, $X(\Gamma, G)$,
but you probably do not have enough background (yet) for this discussion.