An earlier question by Joel David Hamkins asked whether multiplication is implicitly definable in the structure $(\mathbb{N},S)$ of the naturals with successor. Here $R$ is implicitly definable if there is a formula $\phi(\dot{R})$ that is satisfied only if $R = \dot{R}$. Joel's goal was to find a natural counterexample to implicit definability being transitive: $+$ is implicitly definable in terms of $S$, and $\cdot$ is implicitly definable in terms of $+$, and he hoped that $\cdot$ would not be implicitly definable in terms of $S$. Alas, it is, so we need an alternate example.
Question: Is the set of primes implicitly definable in $(\mathbb{N},S)$?
My guess is no, roughly because the set of primes has arbitrarily large gaps with pseudorandom behavior that cannot be captured by $S$ alone. In particular, I would conjecture that given any formula $\phi(P)$ on a predicate $P$ that is satisfied if $P = \textrm{Primes}$, there is some prime $p$ such that $\phi(P - \{p\})$ is true.
If primes is indeed not implicitly definable, it provides a nice counterexample to transitivity. From the earlier question $\cdot$ is implicitly definable from $S$, and primes is explicitly definable from $\cdot$.