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In many places they assume "isotropicity" of the group (i.e. Witt index > 0) to get simplicity of the projectivisation of the derived subgroup (L. Grove, thm 6.31, page 58). In the case of usual SO_n, the Witt index is 0, so the simplicity is not clear.
I know this simplicity criterion (due to Tit's) with BN pair buissness, but the main point is the perfectness of the group. I don't know how to show that SO_n's are perfect.