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@Iosif Pinelis The last question (about $r(t,s)$) is asking about $\exp r$ being positive-definite when $r$ is positive definite. Since $r$ can be written as the sum of a symmetric matrix and a skew-symmetric matrix, and moreover since the positiveness assumption does not concern the skew-symmetric part, you arrive at the question formulated in my answer ($A,S$ business).