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Hopf algebras are pretty easy to motivate, as a not-necessarily-commutative generalization of the ring of functions on an algebraic group (and there are many other ways in which they come up). I like ...

Every commutative $C^*$-algebra is isomorphic to the set of continuous functions, that vanish at infinity, of a locally compact Hausdorff space. Every commutative finite dimensional Hopf algebra is ...