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How to understand $\mathcal{L}BG \simeq G/^{\text{ad}}G$ in term of simplicial sets?

First let $G$ be a topological group and $BG$ its classifying space. Let $\mathcal{L}BG=\text{Map}(S^1, BG)$ be the free loop space of $BG$. We can see that $\mathcal{L}BG$ has the homotopy type of $...