This question is very close to this old MSE question of mine, which is still unanswered.
Is there an (ideally reasonably-natural!) expansion of the structure $(\mathbb{N};+)$ in a finite language whose first-order theory is computable but such that, for each $n$, there is a quantifier-rank-$n$ formula in a single free variable not defining the same set as any $<n$-quantifier-rank formula?
Here quantifier rank is determined by the number of alternations of quantifier types when the formula is put into prenex normal form; so e.g. "$\forall x,y,z\exists w\forall u,v\theta$" has quantifier rank $3$ assuming $\theta$ is quantifier-free.
For example, adjoining exponentiation with base $2$ does not work since its quantifier hierarchy collapses (due to Cherlin/Point, see here). Indeed, all the decidability results I'm familiar with for theories of arithmetic rely on quantifier elimination after some finite expansion by definitions, and so won't help here.