$\DeclareMathOperator{\Hom}{Hom} \DeclareMathOperator{\Sing}{Sing} \DeclareMathOperator{\Top}{Top} \DeclareMathOperator\sSets{sSets}$Is there a category of “sufficiently nice” topological spaces such that the singular simplicial complex functor $\Sing_\bullet:\Top \to \sSets$ is fully faithful ?
Is $\Hom_{\Top}(X,Y)=\Hom_{\sSets}(\Sing_\bullet X, \Sing_\bullet Y)$ for $X$ and $Y$ topological spaces nice enough ?
Is there a good reference for facts like this ?
Note that $X:=\Bbb{Q}$ and $Y:=\Bbb Z$ form a counterexample, as the singular simplicial complex of a totally disconnected space is constant. Thus totally disconnected spaces are not nice enough. See details at Is the singular simplicial functor full.