As Asaf and Joel have observed, the answer to your question is negative. However, there is a sense in which being an elementary submodel of $L_{\omega_1}$ is the only way to "persistently" get elementary submodelhood relations.
Specifically, the following are equivalent:
$L_\alpha\prec L_{\omega_1}$.
There is a club $S\subseteq\omega_1$ such that $L_\alpha\prec L_\beta$ for all $\beta\in S$.
But on the other other hand, if $V=L$ then there is an unbounded $U\subseteq \omega_1$ such that for all $\alpha,\beta\in U$ we have $L_\alpha\equiv L_\beta\not\equiv L_{\omega_1}$ (note that this can't be proved using just a counting argument or forcing + absoluteness). This is a beautiful short application of Tarski's undefinability theorem due to Hjorth, answering question 10.4 of A. Miller. Hjorth's argument, with minor formatting edits from me, is copied below (which I've left hidden to avoid spoilers):
Let $X$ be the set of complete theories that satisfy "everything is countable" and have unboundedly many $\alpha<\omega_1^L$ with $L_\alpha$ realising them. The theory of $L_{\omega_1^L}$ is one such theory, and we will be done if we prove that there are some others. Now $X$ is a definable class in $L_{\omega_1^L}$, and so it must have some other elements or else $L_{\omega_1^L}$ would admit a truth definition ($\varphi$ is true in $L_{\omega_1^L}$ iff the unique element of $X$ contains $\varphi$).