The integral is:
$$f(a) = \int\limits_{-\infty}^\infty \frac{x e^{-a^2 x^2}}{\tanh(x)}dx$$
which seems to converge for all $a>0$. But I don't know how to get a sense of the function $f(a)$ such as writing it as a convergent series. The usual Taylor series has infinity for each term. Any ideas?
Edit:
I believe (using answers below) that when $a$ is close to zero we have (doing a substitution):
$$f(a) = \frac{1}{a^2}\int\limits_{-\infty}^\infty \frac{x e^{-x^2}}{\tanh (x/a)}dx$$
But using $\tanh(x/a)\rightarrow\operatorname{sign}(x)$ as $a\rightarrow 0^+$. So the above should become: $$f(a) \approx \frac{2}{a^2}\int\limits_{0}^\infty x e^{-x^2}dx = \frac{1}{a^2}$$
So that gives the behaviour of $f(a)$ when $a$ is small. But I don't know how to give extra terms. (Also not sure if this is mathematically correct). From numerical calculations I find that near $0$, $$ f(a)\approx \frac{1}{a^2} + \frac{\pi^6}{6} - \frac{\pi^4 }{60}a^2+\frac{\pi^6 }{252}a^4+... = \frac{1}{a^2}\sum\limits_{n=0}^\infty \frac{B_{2n} a^{2n}\pi^{2n}}{n!} $$ although apparently this doesn't converge?
Comment
The answers below are two asymptotic series depending on whether $a$ is small or large. These give good approximations if we truncate the summation before begins to diverge. In the mid-range, when $a^2=1/\pi$, these two sums become term-by-term equal and the closest the truncated sum get to the true answer of $f(1/\sqrt{\pi})$ is to about 1% error. Using both these sums, we can know any value to within about 1%-2% error, and if $a$ is small or large then much more accurately.