$\newcommand\Cov{\operatorname{Cov}}\newcommand\De\Delta$No. Even in the nicest case when $a=0$ and $b=1$, so that $X=W$, we have
$$\Cov(X_t,X_{t+\De t})=t\underset{\De t\to\infty}{\not\longrightarrow}0 \tag{1}\label{1}$$
for any real $t\ge0$.
On the other hand, for any smooth enough $a$ and $b$ and any real $t\ge0$ and $\De_t\ge0$, the random variable $X_{t+\De t}-X_t$ is independent of $X_t$ (and even of the entire pre-history $(X_s\colon s\in[0,t])$), so that
$$\Cov(X_t,X_{t+\De t}-X_t)=0 \tag{2}\label{2}$$
and, moreover,
$$\Cov(X_s-X_r,X_{t+\De t}-X_t)=0 \tag{3}\label{3}$$
for all real $r,s$ in $[0,t]$.
Perhaps, this is the reason for your numerical observations. (The equalities in \eqref{2} and \eqref{3} also follow from the equality in \eqref{1}.)
N.B.: The correct way to write the SDE is this: $dX_t=a(X_t)\,dt+b(X_t)\,dW_t$.