I should preface this question by saying that I strongly suspect the answer is negative, but I couldn't find the counterexample myself.
Say we are working on the unit disc $D \subset \mathbf{R}^n$, where we are given two uniformly elliptic operators with coefficients $A^{ij}$ and $a^{ij}$. (These may be as regular as one needed, for instance at least $C^1$. Moreover for definiteness one might be the identity matrix, say $a^{ij} = \delta^{ij}$.)
Let $U$ and $u$ be two solutions respectively of the divergence-form equations $D_i(A^{ij} D_j U) = 0$ and $D_i(a^{ij} D_j u) = 0$. (Again $U$ and $u$ can be taken as regular as one desires.) We consider their difference $v:= U - u$.
Question. Is there a function $\lambda: D \to [0,1]$ so that $v$ satisfies the 'intermediate' equation $D_i((\lambda A^{ij} + (1 - \lambda) a^{ij}) D_j v) = 0$?
A negative answer would follow for example from the failure of $v$ to satisfy some property of elliptic PDE, the maximum principle being the obvious candidate. As mentioned above, I couldn't find the example that demonstrates this failure. (I suspect there might even exist one where $A^{ij}$ and $a^{ij}$ are constant.)