I know that the group structure on Hom sets can be recovered from biproducts if they exit. Indeed, if $f, g : A \to B$ are two maps then there is a uniquely defined map $f \oplus g : A \oplus A \to B \oplus B$ and then there are diagonal and codiagonal maps giving $$ A \to A \oplus A \to B \oplus B \to B $$ so we get a composition law on Hom sets.
However, if products/coproduct/biproducts don't exist in my category, then I don't see why the Ab-enrichment should be a "property" and not a "structure." Therefore, I am wondering if it possible for some wacky pre-additive category without biproducts to have multiple Ab-enriched structures?