McDuff showed that every connected homotopy type can be realized as the classifying space of a discrete monoid, but the monoid she constructs has lots of idempotents.
Question: Which homotopy types are realized as the classifying space of a right-cancellative discrete monoid?
In the commutative case, my guess would be that $BM \simeq B(M[M^{-1}])$, so that the classifying space is aspherical. But I'm less confident that this happens in the noncommutative case.