We can attack this problem by using Fourier transforms (i.e. characteristic functions). I'll consider
the example in the problem where $X$ is a random variable taking the value $0$ with probability $1/3$, and $4^{k}$ and
$-4^{k}$ with probability $1/4^{k+1}$ (for $k=0$, $1$, $\ldots$). I'll show that the probability that $|X_n|/n >M$ is
about a constant times $1/M$ (more precise result below).
Fix a smooth function $\Phi$ compactly supported in $[-1,1]$
and approximating the characteristic function of that interval. Concretely, suppose $\epsilon$ is small and
$\Phi(x)=1$ on $[-1+\epsilon, 1-\epsilon]$ and is between $0$ and $1$ on the rest of $[-1,1]$. Since $\Phi$ is
smooth, its Fourier transform ${\hat \Phi}(\xi) = \int_{-\infty}^{\infty}\Phi(x) e^{-2\pi i x\xi} dx$ has rapid decay for $|\xi|$ large.
Now let $n$ and $M$ be large and consider
$$
{\Bbb E}\Big(\Phi\Big(\frac{X_n}{nM}\Big)\Big).
$$
Note that
$$
\text{Prob} (|X_n| >nM) \le 1 -{\Bbb E}(\Phi(X_n/(nM))) \le \text{Prob}(|X_n| > (1-\epsilon)nM),
$$
and so our problem is to understand the expectation above. By Fourier inversion,
$$
{\Bbb E}(\Phi(X_n/(nM))) = \int_{-\infty}^{\infty} {\hat \Phi}(\xi) {\Bbb E}\Big( e^{2\pi i \xi X_n/(nM)}\Big) d\xi
= \int_{-\infty}^{\infty} {\hat \Phi}(\xi) \Big( {\Bbb E}\Big( e^{2\pi i \xi X/(nM)}\Big)\Big)^{n} d\xi.
$$
Now we compute that
$$
{\Bbb E}\Big( e^{2\pi i \xi X/(nM)}\Big) = \frac{1}{3} + 2 \sum_{k=0}^{\infty} \frac{1}{4^{k+1}} \cos \Big( \frac{2\pi \xi 4^k}{nM}\Big)
= 1 - 2\sum_{k=0}^{\infty} \frac{1}{4^{k+1}}\Big (1-\cos \Big( \frac{2\pi \xi 4^k}{nM}\Big) \Big).
$$
Now using that $(1-\cos(x)) = O(\min(x^2, 1))$ we see that
$$
\sum_{k=0}^{\infty} \frac{1}{4^{k+1}}\Big (1-\cos \Big( \frac{2\pi \xi 4^k}{nM}\Big) \Big) = O\Big( \frac{|\xi|}{nM}\Big).
$$
Therefore, using $(1-x)^n = 1-nx +O(n^2 x^2)$ for $0\le x\le 1$,
$$
{\Bbb E}(\Phi(X_n/(nM))) = \int_{-\infty}^{\infty} {\hat \Phi}(\xi) \Big( 1- 2n \sum_{k=0}^{\infty} \frac{1}{4^{k+1}}\Big (1-\cos \Big( \frac{2\pi \xi 4^k}{nM}\Big) \Big)
+ O\Big(\frac{\xi^2}{M^2}\Big) \Big) d\xi.
$$
Since ${\hat \Phi}$ has rapid decay, the error term above is $O(1/M^2)$ (with the implied constant depending only on the
fixed function $\Phi$). Using Fourier inversion, we conclude that
$$
{\Bbb E}({\Phi }(X_n/(nM))) = \Phi(0) - n \sum_{k=0}^{\infty} \frac{1}{4^{k+1}} \Big(2 \Phi(0) - \Phi\Big(\frac{4^k }{nM} \Big) -\Phi\Big(-\frac{4^k}{nM}\Big)\Big)
+ O\Big(\frac{1}{M^2}\Big).
$$
Since $\Phi(0)=1$, we get
$$
1- {\Bbb E}({\Phi }(X_n/(nM))) = n \sum_{k=0}^{\infty} \frac{1}{4^{k+1}} \Big(2 - \Phi\Big(\frac{4^k }{nM} \Big) -\Phi\Big(-\frac{4^k}{nM}\Big)\Big)
+ O\Big(\frac{1}{M^2}\Big).
$$
By our choice for $\Phi$, the main term above is
$$
\ge 2n \sum_{k, 4^{k} \ge nM} \frac{1}{4^{k+1}},
$$
and is
$$
\le 2n \sum_{k, 4^{k} \ge (1-\epsilon) nM} \frac{1}{4^{k+1}}.
$$
Thus we have obtained a good understanding of the probability that $|X_n|/n$ is large. Note also that
the precise answer will have discontinuities when $nM$ gets near a power of $4$, but in any case
the probability is about a constant times $1/M$.