Whilst reading 'the book' I stumbled across the following elegant little theorem, due to Gómez-Larrañaga and González-Acuña.
Let $M$ be a closed $3$-dimensional manifold. Then its Lusternik-Schnirelmann category satisifes
$$cat(M)=\begin{cases}1&\text{if}\;\;\pi_1M=\{1\}\\ 2&\text{if}\;\;\pi_1M\;\;\text{is free}\\ 3&\text{otherwise}.\end{cases}$$
I thought this was a pretty neat little characterisation. My question, then, is if anyone has ever sat down and tried to produce a similar statement for 4-manifolds? If possible I would be looking for a pleasingly tenuous connection to some of the smooth invariants that people like to write down.
I'm aware of a few scattered results in the area. For example Dranishnikov, Katz and Rudyak have a joint paper in which they formulate some general statements for higher dimensional manifolds. The book itself also includes a discussion of Cornea, Lupton, Oprea, Tanre and other's work on the relation of the categorical invariants to symplectic topology in general, but again they are not focused necessarily on the 4-dimensional case.