The computer found this, but couldn't prove it.
Let $\psi(n,x)$ denote the polygamma function.
With precision 500 decimal digits we have:
$$ \pi^2 = \frac{1}{4}(15 \psi(1, \frac13) - 3 \psi(1, \frac16)) $$
Is it true?
In machine readable form:
pi^2 == 1/4*(15*psi(1, 1/3) - 3*psi(1, 1/6))