Consider $(\mathbb{C}^2, \omega)$ where $\omega$ is a non-degenerate complex skew-symmetric bilinear form on $\mathbb{C}^2$. Let us write
$V = (\mathbb{C}^2, \omega)$
There are many spaces one can construct from $V$. For instance $Sym^n(V)$ is a vector space endowed with a non-degenerate complex bilinear form (respectively a non-degenerate complex skew-symmetric bilinear form) if n is even (respectively odd). Thus, we have realized $O(2k+1,\mathbb{C})$ and $Sp(2k,\mathbb{C})$ as groups of symmetry of a natural space constructed from $V$.
A more complicated example is $G_2$, which is the group of symmetries of $Sym^6(\mathbb{C}^2)$, endowed with a complex skew-symmetric trilinear form which can be defined using $\omega$ only. See for instance Theorem 1.1 (page 2) in https://arxiv.org/abs/1107.2813, though I am sure it goes back way before (not sure who is the first).
I am still struggling to get $O(2n,\mathbb{C})$ that way, as the group of symmetries of a natural space constructed from $V$, and I wonder whether the remaining exceptional Lie groups can be viewed this way.
I remark that there are more complicated spaces one can build from $V$, such as the kernel of the "symmetrization map":
$Sym^k(\mathbb{C}^2) \otimes Sym^l(\mathbb{C}^2) \to Sym^{k+l}(\mathbb{C}^2)$
or, the kernel of:
$Sym^k(\mathbb{C}^2) \otimes Sym^l(\mathbb{C}^2) \to Sym^{k-l}(\mathbb{C}^2)$
if $k \geq l$, the map being defined by contracting using the symplectic form $\omega$. (I believe that the right term for "natural space constructed from $V$" is a Schur functor, a term I have just met in one of Prof. Robert Bryant's answers to another post).
Edit 1: Allow me please to rephrase a little my question. Prof. @RobertBryant, while your answer is quite helpful, and I particularly thank you for the very nice description of $E_6$ that you have provided, yet what I would like to achieve, if possible, is different, though related.
Does there always exist, for any complex semisimple Lie algebra, a construction/definition/description of a corresponding compact real form, as a group of symmetries of $(W, \sigma)$, where $W$ is a complex vector space and $\sigma$ is a set of structures on $W$, under the conditions that $W$ can be constructed from the standard representation $V = \mathbb{C}^2$ of $SU(2)$ using (symmetrized, skew-symmetrized,...) tensor products of copies of $V$, and $\sigma$ can be constructed using the standard structures on $V$, namely the complex symplectic form $\omega \in \Lambda^2V^*$ and the quaternionic structure $j$ on $V$, which maps $(u,v)$ to $(-\bar{v}, \bar{u})$.
I already know that $Sp(m, \mathbb{R})$, $O(2m+1, \mathbb{R})$ and $G_2$ can be defined as groups of symmetries of some corresponding $(W, \sigma)$, where the latter is constructed from $(V, (\omega, j))$. We note also that $O(4, \mathbb{R})$ can also be defined as the group of symmetries of $(V \otimes V, (\sigma \otimes \sigma, j \otimes j))$. What about $O(2m, \mathbb{R})$ or $Spin(2m, \mathbb{R})$ and the other $4$ exceptional cases?