I claim that $\delta_{n}=2$ for all $n$.
Lemma: For each $n$, and each vector $[x_{1},\dots,x_{n}]^{T}$ with
$x_{1}+\dots+x_{n}=0$, there are matrices $A_{1},\dots,A_{k}$ where
each $A_{i}$ is the convex combination of $2$ permutation matrices and
where $A_{1}\dots A_{k}[x_{1},\dots,x_{n}]^{T}=\mathbf{0}$.
Proof: Let $r$ be the number of non-zero entries in the vector $[x_{1},\dots,x_{n}]^{T}$. Then we shall prove this result by induction on $r$. The result is clear when $r=0,r=1$, so assume $r>1$. Then there is a permutation matrix $A$ such that $A[x_{1},\dots,x_{n}]^{T}=[y_{1},\dots,y_{r-1},y_{r},0,\dots,0]^{T}$ such that $y_{r-1}>0,y_{r}<0$.
Let $t=\frac{y_{r-1}}{y_{r-1}-y_{r}}$.
Then $$(t\cdot I_{n}+(1-t)\cdot\rho_{(r-1,r)})[y_{1},\dots,y_{r-1},y_{r},0,\dots,0]^{T}$$
$$=t[y_{1},\dots,y_{r-1},y_{r},0,\dots,0]^{T}+(1-t)[y_{1},\dots,y_{r-2},y_{r},y_{r-1},0,\dots,0]^{T}=[y_{1},\dots,y_{r-2},y_{r-1}+y_{r},0,\dots,0]^{T}.$$
Therefore, there are matrices $A_{1},\dots,A_{k}$ where
$$A_{1}\dots A_{k}[y_{1},\dots,y_{r-2},y_{r-1}+y_{r},0,\dots,0]^{T}=\mathbf{0}$$ and $A_{i}$ is the convex combination of 2 permutation matrices for $1\leq i\leq k$. Therefore, if we set $A_{k+1}=t\cdot I_{n}+(1-t)\cdot\rho_{(r-1,r)}$ and
$A_{k+2}=A$, then $A_{1}\dots A_{k+2}[x_{1},\dots,x_{n}]^{T}=\mathbf{0}$ and $A_{i}$ is the convex combination of 2 permutation matrices whenever $1\leq i\leq k+2$. Q.E.D.
Theorem: For all $n>1$, we have $N_{n}=A_{1}\dots A_{k}$ for some $k$
and matrices $A_{1},\dots,A_{k}$ such that $A_{i}$ is the convex
combination of $2$ permutation matrices for $1\leq i\leq k$.
Proof: Observe that if $A$ is a doubly stochastic matrix, then $A=N_{n}$ if and only if $A(x_{1},\dots,x_{n})^{T}=\mathbf{0}$ whenever $x_{1},\dots,x_{n}$ are real numbers with $x_{1}+\dots+x_{n}=0$.
Let $V$ be the space of all column vectors $[x_{1},\dots,x_{n}]^{T}$ with
$x_{1}+\dots+x_{n}=0$.
Claim: For all $r$ with $0\leq r<n$, there are matrices $A_{1}\dots A_{k}$ where for $1\leq i\leq k$, the matrix $A_{i}$ is the convex combination of two permutation matrices and where $\text{dim}(V\cap\text{null}(A))\geq r$ where $A=A_{1}\dots A_{k}$.
Proof: We prove this claim by induction on $r$. The case when $r=0$ is trivial. Suppose now that $A=A_{1}\dots A_{k}$ where $\text{dim}(V\cap\text{null}(A))\geq r$ and where $A_{i}$ is the convex combination of two $n\times n$ permutation matrices for $1\leq i\leq r$. Now, if $\dim(V\cap\text{null}(A))=n-1$, then the induction step is complete. If $\dim(V\cap\text{null}(A))<n-1$, then let $[x_{1},\dots,x_{n}]^{T}\in V\setminus\text{null}(A)$, and let
$[y_{1},\dots,y_{n}]^{T}=A[x_{1},\dots,x_{n}]^{T}$. Then there are matrices $A_{-r}\dots A_{0}$ such that $A_{-r}\dots A_{0}[y_{1},\dots,y_{n}]^{T}$ and $A_{i}$ is the convex combination of two permutation matrices for $-r\leq i\leq 0$. Therefore, if $B=A_{-r}\dots A_{0}A_{1}\dots A_{k}$, then $\dim(V\cap\text{null}(B))\geq r+1$.
Our claim has been proven.
The result follows from our claim in the case that $r=n-1$. Q.E.D.
We are in fact able to produce the following explicit factorization of $N_{n}$
Let $$C_{n,r}=\frac{1}{r+1}(I_{n}+r\rho_{(r,r+1)}).$$ Let $$D_{n,r}=C_{n,1}\dots C_{n,r-1}.$$
Theorem: Suppose $n>0$. Then $N_{n}=D_{n,n}\dots D_{n,2}.$
Proof outline: We use induction. Using the induction hypothesis, we have
$$D_{n,n-1}\dots D_{n,2}=\begin{bmatrix}N_{n-1} & \mathbf{0}\\ \mathbf{0}&I_{1}
\end{bmatrix}.$$
Set $A=D_{n,n-1}\dots D_{n,2}$. Then $\dim(\ker(A)\cap V)=n-2$.
Now, $[-1,\dots,-1,n-1]^{T}\in V\setminus\ker(A)$, however, $$D_{n,n-1}A[-1,\dots,-1,n-1]^{T}=D_{n,n-1}[-1,\dots,-1,n-1]^{T}=\mathbf{0},$$ so
$\dim(\ker(D_{n,n-1}A)\cap V)>n-2$, but this is only possible if
$V\subseteq\ker(D_{n,n-1}A)$. This implies that $D_{n,n-1}A=N_{n}$. Q.E.D.
There are other decompositions as well.
Theorem: Suppose $n>0$. Then $D_{n,n}^{n-1}=N_{n}$.